Structure and Mechanical Properties of Triblock Copolymer Poly[styrene-<i>block</i>-(ethylene-<i>co</i>-propylene)-<i>block</i>-styrene] and Asphalt Mixture

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  • アスファルトとポリ[スチレン-<i>block</i>-(エチレン-<i>co</i>-プロピレン)-<i>block</i>-スチレン]ブロック共重合体ブレンドの力学的性質と相構造
  • Structure and Mechanical Properties of Triblock Copolymer Poly[styrene-block-(ethylene-co-propylene)-block-styrene] and Asphalt Mixture.

Abstract

Structure and mechanical properties of the mixtures of asphalt and the triblock copolymer poly[styrene-block-(ethylene-co-propylene)-block-styrene](SEPS) were studied by differential scanning calorimetry (DSC), needle penetration and softening point, and tensile strength measurements. From the measurements of glass transition temperature in the mixture of asphalt components and SEPS, maltene, the soluble fraction extracted from the asphalt in heptane, was partially miscible with the ethylene/propylene block of SEPS, whereas asphaltene, the insoluble fraction in heptane, partially miscible with the polystyrene block. The mixture of asphalt and SEPS was a partially miscible system. The viscosity, needle penetration and tensile strength of the mixtures may be improved in the low concentration of SEPS (e.g. 5–10 wt%). A microstructure model of SEPS-asphalt blend system with the lower amount of SEPS was proposed and efficaciously approached to explain the resulting phenomena. The small amount of SEPS in asphalt seem to act as a compatibilizer and emulsify the two components of asphalt to make a mechanically stable network.

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