Addition Reaction of Poly(thiomethacrylic S-ester)s with Epoxy Compound

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  • SATO Kazuya
    Department of Applied Chemistry, Faulty of Engineering, Kanagawa Uni versity;
  • KOBAYASHI Motoki
    Department of Applied Chemistry, Faulty of Engineering, Kanagawa Uni versity;
  • KAMEYAMA Atsushi
    Department of Applied Chemistry, Faulty of Engineering, Kanagawa Uni versity;
  • NISHIKUBO Tadatomi
    Department of Applied Chemistry, Faulty of Engineering, Kanagawa Uni versity;

Bibliographic Information

Other Title
  • ポリ(チオメタクリル酸S一エステル)類とエポキシ化合物との付加反応
  • Addition Reaction of Poly(thimethacrylic S-ester)s with Epoxy Compound.

Description

Addition reaction of polymer bearing pendant S-thioester moiety with epox stigated using quaternary onium salts or cesium halides as catalysts. y cAoms posuhnodw n wains inve scheme ( 1), polymers having pendant (S-thioester moieties such as pol acrylate) (PPTM) and poly(S-benzyl thiomethacrylate) (PBTM) we rye( S-pprheepnayrle d tbhyio mteh-eth radical) polymerization of the corresponding monomers. PPTM has higher reactivity than PBTM and poly(phenyl methacrylate) (Table 5). Addition reaction of PPTM with phenyl grloymcididyel eothr er tetr(aPpGhEen)v yelrpyph roosscpmeheoodonetihdul my unudnedr erb hroigmmhii ldde r earcetaaicso tnio tnh e temccopanetdaraliyttiusortnses. uuOssiinnn gg thtceee tsriauobmtuht eyrl a fmlumhoarindde o, niautshm isp a brr oecaecetidoend catalyesst. t catalyFtiucr theramctoivreit, y in it adwdiatiso n fournedac tiotnh at of cePsPiuTmM flwuoitrhid eP-G1E8- cr(oTwnab-6le 8). complex ha s the high

Journal

  • NIPPON KAGAKU KAISHI

    NIPPON KAGAKU KAISHI 1992 (8), 834-839, 1992-08-10

    The Chemical Society of Japan

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