Preparation and Properties of β-Diketone and β-Keto Ester Complexes of Bismuth(III), Strontium(II), and Calcium(II)

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  • Dol Masaru
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
  • HIRAI Kentaro
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
  • NAKAMURA Fusao
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
  • GUNJI Takahiro
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
  • NAGAO Yukinori
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
  • MISONO Takahisa
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
  • ABE Yoshimoto
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo

Bibliographic Information

Other Title
  • ビスマス(III),ストロンチウム(II)およびカルシウム(III)のβ-ジケトンとβ-ケトエステル錯体の合成と性質
  • Preparation and Properties of .BETA.-Diketone and .BETA.-Keto Ester Complexes of Bismuth(III), Strontium(II), and Calcium(II).

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Description

Dipivaloylmethanato (dpm), acetylacetonato (acac), and ethyl acetoacetato (etac) complexes of bismuth(III), strontium (II), and calcium (III) with a high purity as a precursor to BSCCO superconducting oxide were prepared. Bismuth complexes were obtained by the reaction of bismuth trichloride with Hdpm in the presence of triethylamine or by the reaction of bismuth triethoxide with Hacac and Hetac. On the other hand, strontium and calcium complexes were prepared by the reaction of metals with the ligands. The solubilities and spectral analyses of these complexes were investigated.

Journal

  • NIPPON KAGAKU KAISHI

    NIPPON KAGAKU KAISHI 1995 (10), 802-808, 1995-10-10

    The Chemical Society of Japan

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