Reaction Rate of Ti0.18Zr0.84Cr1.0Fe0.7Mn0.3Cu0.057 to Use for the Heat Driven Type Compact Metal Hydride Refrigerator
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- BAE Sang-chul
- Institute of Ocean Energy, Saga University
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- KATSUTA Masafumi
- Department of Mechanical Engineering, Waseda University
書誌事項
- タイトル別名
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- Reaction Rate of Ti<sub>0.18</sub>Zr<sub>0.84</sub>Cr<sub>1.0</sub>Fe<sub>0.7</sub>Mn<sub>0.3</sub>Cu<sub>0.057</sub> to Use for the Heat Driven Type Compact Metal Hydride Refrigerator
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説明
Our final goal of this study is to develop the heat driven type compact metal hydride (MH) refrigeration system for the vending machine and the show case, and to attain a refrigeration temperature of 243 K by using a heat source of about 423K. The reaction rate of the MH to use for the heat source, MH used for heat source is studied firstly because the MH refrigeration system consists of two MHs, one is used for the heat source and the other is used for the cooling load extracting. As for the reaction rate in the hydriding process, initially, a rapid surface reaction, governed by the relation 1-(1-F )1/3=kht . After the MH surface has been covered by hydride, the reaction becomes diffusion controlled with the relation 1-3(1-F ' )2/3+2(1-F ' )=k'ht . The reaction rates, kh and k'h , are exponentially proportional to the pressure difference and increase with temperature. And, as for the dehydriding process, it is found out that the rate-controlling step is uniquely diffusion reaction. The dehydriding reaction rate is exponentially proportional to the pressure difference and the initial reacted fraction, and increases with temperature. Finally, on the basis of these experimental results, the brand new rate correlations are reasonably derived. The predicted results for this correlation are in successfully agreement with the experimental ones.
収録刊行物
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- 日本伝熱学会論文集
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日本伝熱学会論文集 14 (1), 1-8, 2006
社団法人 日本伝熱学会
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詳細情報 詳細情報について
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- CRID
- 1390001204413937408
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- NII論文ID
- 10017276144
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- NII書誌ID
- AA11358679
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- ISSN
- 18822592
- 09189963
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- NDL書誌ID
- 7888966
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- CiNii Articles
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- 使用不可