インデンの電解重合

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  • Electroinitiated Polymerization of Indene

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Electroinitiated polymerization of indene was studied in various solvents and it was found that the polymerization proceed only in an acetic anhydride solution containing lithium perchlorate. From the results of the IR and UV spectroscopic studies, it was presumed that the structure of polymers formed in the acetic anhydride solution were similar to that produced by the usual cationic polymerization, and that a small number of acyl and/or acetyl groups existed in the polymers. Moreover, it was speculated the polymerization initiated by electro- lysis was proceed by a cationic mechanism.

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