水溶液中における光学活性アジリジンの開環反応

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書誌事項

タイトル別名
  • Ring-Opening Reaction of Optically Active Aziridine in Water
公開日
1989-09-10
DOI
  • 10.1246/nikkashi.1989.1648
  • 10.1002/chin.199009137
公開者
公益社団法人 日本化学会

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説明

Ring-opening reaction of optically active 2-ethylaziridine in water was found to give 1-(2-ethy1-1-aziridiny1)-2-butanaminek N-(2-aminobuty1)-1-(2-ethyl-1-aziridinyl-2-butanamine, and oligomers of 2-ethylaziridine. The structures of the products were elucidated on the basis of their infrared spectra and mass spectra. In this ring-opening reaction, the original configuration in the starting aziridine was retained in these products, suggesting the occurrence of N-CH12 bond cleavage in 2-ethylaziridine.

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