The Electrochemical Behavior of the Purine Bases and Their Nucleosides in N, N-Dimethylformamide
-
- YAO Toshio
- Department of Applied Chemistry, College of Engineering, University of Osaka Prefecture
-
- WASA Tamotsu
- Department of Applied Chemistry, College of Engineering, University of Osaka Prefecture
-
- MUSHA Soichiro
- Department of Applied Chemistry, College of Engineering, University of Osaka Prefecture
Bibliographic Information
- Other Title
-
- 瓦ハ乙ジメチルホルムアミド溶媒中におけるプリン塩基とそれらのヌクレオシドの電気化学的挙動
- N,N-ジメチルホルムアミド溶媒中におけるプリン塩基とそれらのヌクレオシドの電気化学的挙動(ノート)
- N N ジメチルホルムアミド ヨウバイチュウ ニ オケル プリン エンキ ト
- N,N‐ジメチルホルムアミド溶媒中におけるプリン塩基とそれらのヌクレオシドの電気化学的挙動
Search this article
Abstract
The electrochemical reduction of the purine bases and their nucleosides in DMF has been investigated by polarography, cyclic voltammetry, and controlled-potential electrolysis. In neutral DMF solutions, these purine bases are initially reduced in a one-electron, diffusion- controlled process at a fairly negative potential to produce an unstable radical anion, which then takes a proton from parent purine to produce a free radical and an anion. The free radical is probably deactivated by fast dimerization to form dimer, or by chemical reaction which is followed by a further one-electron reduction. The reaction of anion with mercury at the electrode produced an oxidation wave.
Journal
-
- NIPPON KAGAKU KAISHI
-
NIPPON KAGAKU KAISHI 1976 (4), 704-706, 1976-04-10
The Chemical Society of Japan
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1390001204418255744
-
- NII Article ID
- 130004155608
-
- NII Book ID
- AN00186595
-
- COI
- 1:CAS:528:DyaE28XktFWls7g%3D
-
- ISSN
- 21850925
- 03694577
-
- NDL BIB ID
- 1708009
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed