ペンタシアノコバルト錯体を用いるミルセン,アロオシメンの水素化反応

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  • Hydrogenation of Myrcene and Alloocimene by Pentacyanocobaltate(II)

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Geometric isomers of 2, 6-dimethyl-2, 6-octadiene and ocimene were obtained from myrcene by the, hydrogenation and isomerization reaction using pentacyanocobaltate(g) as a catalyst. In the case of alloocimene, 2, 6-dimethyl-2, 4-octadiene was obtained. This octadiene was no more hydrogenated From these resglts, the reactivity of the conjugated double boad ih these reactions was discussed.

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