イオン交換法による同位体効果と同位体分離の研究

DOI

書誌事項

タイトル別名
  • Isotope Effects and Isotope Separation Studied by Means of Ion Exchange Processes

抄録

Ion exchange is well known as an excellent technique for chemical separation and applicable even for separation of isotopes. The present paper describes the principle of isotope effects in chemical exchange equilibrium, and the application to the separation of isotopes by using ion exchange resins. Separation coefficients and height equivalent to a theoretical plate have been determined for the experimental systems at different conditions. In particular, flow rate dependence of HETP has been studied on 15N enrichment processes. The study has been extended to the isotope effects of more heavier elements, such as transition elements, lanthanoid and uranium. The isotope effects in complex formation of transition elements have shown to be relatively smaller than those of electron exchange reactions observed by redox chromatography using anion exchange resin. The strange isotope effects observed for U (IV) -U (VI) electron exchange reaction has been elucidated as the isotope effects due to the electron-nuclear interactions.

収録刊行物

詳細情報 詳細情報について

  • CRID
    1390001204435026048
  • NII論文ID
    130004162359
  • DOI
    10.5182/jaie.15.68
  • ISSN
    18843360
    0915860X
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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