Electrostatic Approach to Chromatographic Retention of Ionic Solutes

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The interaction of an ionic solute with a charged surface has been interpreted with an appropriate model derived on the basis of electrostatic theories. The electrostatic effects should play important roles in ion-exchange chromatography, but have not been well involved in the derivation of a retention model. The model proposed in this paper, which is derived based on an electrostatic theory, is capable of reasonable explanation of the retention of ionic solutes having different molecular sizes.

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