Observation of Iron-valence Detrapping in Mixed-valence Trinuclear Heterometal Pentafluorobenzoate Cluster Complex Cr<sup>3+</sup>Fe<sup>3+</sup>Fe<sup>2+</sup>O(C<sub>6</sub>F<sub>5</sub>COO)<sub>6</sub>(C<sub>5</sub>H<sub>5</sub>N)<sub>3</sub>·0.5C<sub>5</sub>H<sub>5</sub>N·CH<sub>2</sub>Cl<sub>2</sub> by <sup>57</sup>Fe-Mössbauer Spectroscopy
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- Ogiso Ryo
- Daido University
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- Sakai Yoichi
- Daido University
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- Onaka Satoru
- Daido University Nagoya Institute of Technology
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- Nakamoto Tadahiro
- Toray Research Center
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- Takayama Tsutomu
- Daido University
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- Takahashi Masashi
- Toho University
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説明
A novel mixed-valence trinuclear heterometal pentafluorobenzoate cluster complex Cr3+Fe3+Fe2+O(C6F5COO)6(C5H5N)3·0.5C5H5N·CH2Cl2 was synthesized, and its 57Fe-Mössbauer spectra were measured with a temperature range of 78 to 298 K. It has been revealed that just one apparent valence state of Fe2.5+ was observed at room temperature.
収録刊行物
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- Ｊｏｕｒｎａｌ ｏｆ Ｎｕｃｌｅａｒ ａｎｄ Ｒａｄｉｏｃｈｅｍｉｃａｌ Ｓｃｉｅｎｃｅｓ
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Ｊｏｕｒｎａｌ ｏｆ Ｎｕｃｌｅａｒ ａｎｄ Ｒａｄｉｏｃｈｅｍｉｃａｌ Ｓｃｉｅｎｃｅｓ 13 (1), N1-N3, 2013
一般社団法人 日本放射化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204481545728
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- NII論文ID
- 130004567672
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- ISSN
- 18835813
- 13454749
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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