Development of Fluoroalkyl End-capped Oligomeric Nanocomposites-encapsulated Metal Nanoparticles

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  • 金属ナノ粒子をカプセル化させたフルオロアルキル基含有オリゴマーナノコンポジット類の開発
  • キンゾク ナノ リュウシ オ カプセルカ サセタ フルオロアルキルキ ガンユウ オリゴマーナノコンポジットルイ ノ カイハツ

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Abstract

<p>Two fluoroalkyl end-capped oligomers [RF-(M)n-RF] were prepared by reaction of fluoroalkanoyl peroxide with traditional radical polymerizable monomers (M). These fluoroalkyl end-capped oligomers can be classified according to their structure into new ABA triblock-type fluorinated polysoaps, and form the nanometer size controlled self-assembled molecular aggregates with the aggregation of terminal fluoroalkyl segments in aqueous and organic media. Fluoroalkyl end-capped oligomeric aggregates can interact with a variety of guest molecules such as gold, silver and copper nanoparticles to afford the corresponding fluorinated oligomers/guest molecules nanocomposites. The preparation and applications of these new fluorinated oligomers/guest molecules nanocomposites are reviewed in this articles.</p>

Journal

  • Oleoscience

    Oleoscience 14 (2), 55-66, 2014

    Japan Oil Chemists' Society

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