Amphiphilic Diblock Copolymers Composed of a Hydrophobic Pendant Dendron-containing Block

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  • YUSA Shin-ichi
    Department of Materials Science and Chemistry, University of Hyogo

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Other Title
  • 疎水性デンドロンを側鎖結合したブロックを含む両親媒性ジブロック共重合体
  • ソスイセイ デンドロン オ ソクサ ケツゴウ シタ ブロック オ フクム リョウシンバイセイ ジブロック キョウ ジュウゴウタイ

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Description

<p>Well-defined amphiphilic diblock copolymers composed of a hydrophilic linear polymer block and hydrophobic block bearing pendent dendritic moieties were synthesized via reversible addition-fragmentation chain transfer (RAFT) controlled/living radical polymerization. These amphiphilic diblock copolymers formed interpolymer aggregates due to hydrophobic interactions between dendron moieties in water. The hydrophobic domains formed from the aggregates recognized small shape difference of hydrophobic small guest molecules. The amphiphilic diblock copolymers formed inter-micellar aggregates or vesicles depending on the composition of hydrophilic linear and hydrophobic dendritic blocks.</p>

Journal

  • Oleoscience

    Oleoscience 14 (2), 67-72, 2014

    Japan Oil Chemists' Society

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