Experimental Investigation on the Effect of Forced Temperature Cycling Operation on a Chemical Reaction

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  • 温度周期操作を利用した反応制御技術の実験的検討
  • オンド シュウキ ソウサ オ リヨウシタ ハンノウ セイギョ ギジュツ ノ ジッケンテキ ケントウ

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The present study aims at developing a new chemical reactor for forced temperature cycling at a low energy cost. Forced temperature cycling is an attractive mode of chemical reactor operation, since it can achieve higher conversion and selectivity for a variety of chemical reactions than steady-state operations. However, there are only limited number of experimental investigation on the effects of forced temperature cycling on chemical reactions. This is because a large amount of energy is needed to quickly change the reactor temperature. With the reactor developed in this study, only 9 W of electric energy was required to achieve forced temperature cycling. In a sample case of the cycling operation for propylene oxidation, it was demonstrated experimentally that the selectivity and conversion can be controlled by employing the forced temperature cycling.

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