溶媒抽出の新展開　　β‐ジケトン‐中性有機リン化合物混合系抽出剤によるリチウムの抽出平衡における抽出剤の疎水性の影響

DOI Web Site Web Site 被引用文献5件 参考文献7件

書誌事項

タイトル別名
  • Recent Research Development in Solvent Extraction. Effect of Hydrophobicity of Extractant on Extraction Equilibrium of Lithium with A Mixture of .BETA.-Diketone and Neutral Phosphorus Compounds.
  • ベータ ジケトン チュウセイ ユウキ リン カゴウブツ コンゴウケイ チュウシュツザイ ニ ヨル リチウム ノ チュウシュツ ヘイコウ ニ オケル チュウシュツザイ ノ ソスイセイ ノ エイキョウ

この論文をさがす

抄録

Using three kinds of novel β-diketone of different alkyl-chain length (1-phenyl-1, 3-octanedione, 1-phenyl-1, 3-tetradecanedione and 1-phenyl-1, 3-icosanedione) and four kinds of neutral phosphorus compounds of different alkyl-chain length (tri-n-butylphosphine oxide, tri-n-octylphosphine oxide), tri -n-butyl phosp ate and tris (2-ethylhexyl) phosphate, the extraction equilibrium of lithium was investigated, and the synergistic effect of these extraction systems was examined, in order to determine the optimum extraction system for lithium.<BR>It is found that lithium is synergistically extracted by the mixture of β-diketone and neutral phosphorus compounds, and that the ability of lithium extraction with the synergistic reagent of trialkylphosphine oxide is higher than that with tri-alkylphosphate. However, the effect of alkyl-chain length of β-diketone on the extraction equilibrium constants is negligibly small. These results are confirmed by molecular modeling of the extractants and synergistic reagents.

収録刊行物

被引用文献 (5)*注記

もっと見る

参考文献 (7)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ