書誌事項
- タイトル別名
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- Kinetics of Oxidation of Benzyl Alcohol with Solid Phase Transfer Catalyst
- コタイ ソウカン イドウ ショクバイ ニヨル ベンジルアルコール ノ サンカ
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Oxidation of benzyl alcohol in toluene (organic phase) by sodium hypochlorite in distilled water (aqueous phase) was investigated at 303K in a batch reactor containing anion exchange resin (solid phase). It was confirmed by simultaneous measurements of concentration of benzyl alcohol in both the organic phase and the aqueous phase that its concentration in the aqueous phase was always in equilibrium with that in the organic phase. The reaction took place in the aqueous phase and on the solid phase and the reaction rates were of first order with respect to the solute (benzyl alcohol or benzaldehyde). No reaction occurred in the organic phase. The equilibrium constants of adsorption obtained from the experiments with reactions were in good agreement with those from the adsorption experiments without reactions.
収録刊行物
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- 化学工学論文集
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化学工学論文集 9 (1), 58-63, 1983
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204510424448
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- NII論文ID
- 130000881594
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- NII書誌ID
- AN00037234
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- ISSN
- 13499203
- 0386216X
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- NDL書誌ID
- 2578844
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可