Effect of Sulfur Dioxide Partial Pressure and Reaction Temperature on the Product Composition of the Bunsen Reaction

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  • Imai Yoshiyuki
    Nuclear Science and Energy Directorate, Japan Atomic Energy Agency
  • Nakajima Hayato
    Nuclear Science and Energy Directorate, Japan Atomic Energy Agency
  • Kubo Shinji
    Nuclear Science and Energy Directorate, Japan Atomic Energy Agency
  • Onuki Kaoru
    Nuclear Science and Energy Directorate, Japan Atomic Energy Agency

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  • ブンゼン反応の生成物組成に対する二酸化硫黄分圧および反応温度の影響
  • ブンゼン ハンノウ ノ セイセイブツ ソセイ ニ タイスル ニサンカ イオウ ブンアツ オヨビ ハンノウ オンド ノ エイキョウ

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Abstract

The effect of sulfur dioxide partial pressure and reaction temperature on the composition of the poly-hydriodic acid solution produced in the Bunsen reaction, is a unit reaction in the IS process for thermochemical hydrogen production, was studied experimentally under iodine saturation. The ratio of (HI/(HI+H2O)) of the poly-hydriodic acid solution assuming an ideal desulfurization was increased with sulfur dioxide partial pressure and reaction temperature. An experimental equation for the ratio of (HI/(HI+H2O)) was obtained as a function of sulfur dioxide partial pressure and reaction temperature.

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