Equilibria and Mathematical Models of Extraction of Citric Acid with Isodecanol/n-Paraffins Solutions of Trioctylamine.
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- Poposka Filimena A.
- Faculty of Technology and Metallurgy, The “Sv. Kiril i Metodij” University
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- Nikolovski Kostadin
- Faculty of Technology and Metallurgy, The “Sv. Kiril i Metodij” University
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- Tomovska Radmila
- Faculty of Technology and Metallurgy, The “Sv. Kiril i Metodij” University
書誌事項
- タイトル別名
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- Equilibria and Mathematical Models of E
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Extraction equilibria of citric acid from aqueous solutions with trioctylamine in isodecanol/n-parafrins mixtures, were studied as a function of acid, amine and isodecanol concentrations at 25°C. The equilibrium data were interpreted by “chemical modeling” approach in which existence of (1,1) and (1,2) acid-amine complexes in the organic phase, were assumed. The corresponding equilibrium constants, which represent the experimental results the best, were determined.<BR>Simpler mathematical model which refer to modified Langmuir isotherm, was also used for interpretation of the equilibrium data. Extraction constants and overall acid stoichiometric coefficient, which represent the experimental results the best, were determined. This mathematical form could be suitable in the analysis and design of the process in dynamic conditions.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 30 (5), 777-785, 1997
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204564859264
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- NII論文ID
- 130000020763
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- NII書誌ID
- AA00709658
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- COI
- 1:CAS:528:DyaK2sXntVKku74%3D
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- ISSN
- 18811299
- 00219592
- http://id.crossref.org/issn/00219592
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- NDL書誌ID
- 4326516
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可