Measurement and Prediction of Mutual Diffusion Coefficients for Acrylic Adhesive-Methyl Propyl Ketone System.

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  • Kobuchi Shigetoshi
    Department of Applied Chemistry and Chemical Engineering, Yamaguchi University
  • Kumada Makoto
    Department of Applied Chemistry and Chemical Engineering, Yamaguchi University
  • Fujimura Kenji
    Department of Applied Chemistry and Chemical Engineering, Yamaguchi University
  • Komatsubara Hideaki
    Department of Applied Chemistry and Chemical Engineering, Yamaguchi University
  • Arai Yasuhiko
    Department of Chemical Systems and Engineering, Graduate School of Engineering, Kyushu University

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  • Measurement and Prediction of Mutual Di

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Abstract

Mutual diffusion coefficients for an acrylic adhesive-methyl propyl ketone system were measured at 313.15 K, 323.15 K and 333.15 K by using a sorption and desorption method, and are predicted by the free volume theory of Duda et al. which was modified by Iwai et al. The six model parameters out of eight required to predict the mutual diffusion coefficients are estimated by adopting a previous method from the physical properties of methyl propyl ketone. The predicted values are in fairly good agreement with the experimental results.

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