Prediction of Vapor–Liquid Equilibria of Binary Systems at Reduced Pressures by Using Wilson Equation with Parameters Estimated from Pure-Component Properties

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  • Kobuchi Shigetoshi
    Department of Environmental Science and Engineering, Graduate School of Science and Engineering, Yamaguchi University
  • Yonezawa Setsuko
    Department of Chemical Engineering, Faculty of Engineering, Kyushu University

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A simple method GC-W for estimating the Wilson parameters from pure-component properties alone has been adopted to predict the vapor–liquid equilibria of binary systems at reduced pressures. The various binary systems containing non-polar and polar molecules have been studied. The prediction performances obtained are examined and discussed in comparison with UNIFAC.

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