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- Inaba Megumu
- Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology
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- Murata Kazuhisa
- Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology
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- Takahara Isao
- Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology
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- Liu Yanyong
- Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology
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Fast pyrolysis of woody biomass was carried out without and with zeolite catalyst, and the correlation between the distribution of products and the character of catalysts was investigated. Eucalyptus was used as a model of woody biomass. In the case of noncatalyst pyrolysis, the main products were oxygenated compounds such as phenols and aldehydes. Zeolite catalysts chiefly favored the formation of aromatic hydrocarbons, both with and without O-atoms. H-ZSM-5 and H-beta zeolites were especially efficient for the formation of nonoxygenated aromatic compounds. However, high Si/Al2 ratio in H-ZSM-5 depressed the formation of nonoxygenated aromatics, while high Si/Al2 ratio in H-beta maintained the high yield of nonoxygenated aromatics. On the other hand, H-mordenite, USY, SAPO-34, 4A, 13X, and Ti-silicate showed a moderate catalytic activity for the formation of oxygenated as well as nonoxygenated aromatic compounds because of the moderate catalytic properties. Strong solid acidity (H-ZSM-5, H-beta, H-mordenite) favors the deoxygenation reaction. Large micropore diameter and three-dimensional microstructure (H-beta, USY) have advantages, because the intermediates can contact the active sites inside the micropore.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 47 (4), 345-351, 2014
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204569226752
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- NII論文ID
- 130003390893
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- NII書誌ID
- AA00709658
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- COI
- 1:CAS:528:DC%2BC2cXhtlGksbvI
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 025602027
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
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- 抄録ライセンスフラグ
- 使用不可