Dispersion Control of Nano-Particles and the Effect of the Coating Condition on the Performance of Proton-Exchange Membrane Fuel Cells (PEMFCs)
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- Mustafa
- Department of Chemical Science and Engineering, Kobe University
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- Usui Hiromoto
- Department of Chemical Science and Engineering, Kobe University
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- Shige Ibuki
- Department of Chemical Science and Engineering, Kobe University
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- Suzuki Hiroshi
- Department of Chemical Science and Engineering, Kobe University
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- Kobayashi Tetsuhiko
- National Institute of Advanced Industrial Science and Technology
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- Miyazaki Yoshinori
- National Institute of Advanced Industrial Science and Technology
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- Ioroi Tsutomu
- National Institute of Advanced Industrial Science and Technology
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- Yasuda Kazuaki
- National Institute of Advanced Industrial Science and Technology
この論文をさがす
説明
It is known that the particle characteristics and method of coating affect the performance of the electrode in PEMFC technology. The slurry to be used for the preparation of the PEMFC electrode is the suspension of carbon-supported Pt nano-particles (Pt/C) in a Nafion solution. The agglomeration nature of this slurry is obtained both experimentally and theoretically. Information on slurry dispersion is compared with the cross sectional SEM image of the membrane. It is certified that there exists a good correlation between agglomeration characteristic length and the void diameter observed in SEM images. The evaluation of PEMFC electrode performance is done by using several kinds of electrode membranes prepared under different coading speeds. Slight increases both in cell voltage and internal resistance are observed for the case of cathode performance experiments according to the increase of the coating speed. On the other hand, no effect of the coating speed is detected for the case of anode performance experiments due to the cell voltage results were affected mainly by the electrocatalytic activity of the cathode, which results in no effect of the agglomeration. It is concluded that higher coating speed is preferable to get good PEMFC electrode performance within the range of the present experimental conditions.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 37 (1), 31-39, 2004
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204569560960
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- NII論文ID
- 10013338759
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- NII書誌ID
- AA00709658
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- COI
- 1:CAS:528:DC%2BD2cXpvVGlsQ%3D%3D
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 6819371
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
