Ultrasonic Effects on Electrolysis of MV2+ in Surfactant and Polymer Solutions
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- Aita Tadahiro
- Department of Materials Science and Engineering, Yamagata University
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- Wagatsuma Shinya
- Department of Materials Science and Engineering, Yamagata University
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- Hino Eri
- Department of Materials Science and Engineering, Yamagata University
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- Higuchi Takeshi
- Department of Materials Science and Engineering, Yamagata University
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- Sato Shimio
- Department of Materials Science and Engineering, Yamagata University
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Ultrasonic effects on electrolysis of methyl viologen (MV2+) in surfactant and polymer solutions were investigated using an ultrasonic vibrating electrode (USVE). Addition of an anionic polymer or surfactants decreased the efficiency of the electrolysis of MV2+ due to a complex formation between MV2+ and the additives and, at a certain [additive]/[MV2+] ratio, the complex was adsorbed on the electrode. CV measurements using the USVE showed that ultrasonic irradiation increased the efficiency of the electrolysis greatly but was not able to avoid the adsorption of the complex on the electrode. Optical reflection measurements around the USVE indicated that the ultrasonic irradiation caused little change in the concentration of free MV2+ around the electrode. The results showed that the ultrasonic irradiation increased the efficiency of the electrolysis by promotion of mass transport around the electrode, while it was doubted that the irradiation increased the efficiency through decomposition of the complexes.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 41 (6), 447-452, 2008
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204569902080
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- NII論文ID
- 130000018873
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- NII書誌ID
- AA00709658
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 9544380
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
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- 使用不可