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- Hahm Hyun-Sik
- Division of Chemical and Ceramic Engineering, Myongji University
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- Park Eun-Seok
- Division of Chemical and Ceramic Engineering, Myongji University
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- Cheon Han-Jin
- Division of Chemical and Ceramic Engineering, Myongji University
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- Kim Young-Kuk
- Division of Chemical and Ceramic Engineering, Myongji University
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- Lim Yun-Soo
- Division of Chemical and Ceramic Engineering, Myongji University
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- Kim Myung-Soo
- Division of Chemical and Ceramic Engineering, Myongji University
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- Park Hong-Soo
- Division of Chemical and Ceramic Engineering, Myongji University
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抄録
Methanol was synthesized by the partial oxidation of methane with various oxide catalysts. The reaction was carried out using a pyrex-lined fixed bed reactor at 723–753 K and 20–46 bar, while changing the flow rate and feed gas ratios. The adsorption and desorption characteristics of oxygen were examined with an O2-TPD experiment. Bi-Cs-Mg-Cu-Mo catalyst was found to be the most suitable for methanol synthesis. It appeared that a catalyst that can easily provide lattice oxygen is more suitable for methanol synthesis. The methane conversion and methanol selectivity increased with the temperature. The methane conversion increased with the oxygen concentration, while the methanol selectivity decreased with an increasing oxygen concentration. The feed flow rate did not exhibit any significant effects on methane conversion and methanol selectivity.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 37 (2), 152-157, 2004
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204570172928
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- NII論文ID
- 10013339082
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- NII書誌ID
- AA00709658
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- COI
- 1:CAS:528:DC%2BD2cXhvFelsbs%3D
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 6862929
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
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- 抄録ライセンスフラグ
- 使用不可