Stereoselective Synthesis of <I>cis</I>-2,3-Diarylaziridine by Rearrangement of Aryl-Substituted <I>N</I>-(Silylmethyl)imine

  • Komatsu Mitsuo
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Ohno Mitsuru
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Tsuno Shingo
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Ohshiro Yoshiki
    Department of Applied Chemistry, Faculty of Engineering, Osaka University

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Description

Thermal rearrangement of aryl-substituted N-(silylmethyl)imines to N-silylaziridines with high cis-selectivity was revealed and workup of the products readily led to cis-aziridine derivatives.

Journal

  • Chemistry Letters

    Chemistry Letters 19 (4), 575-576, 1990

    The Chemical Society of Japan

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