Initial Process of Photoinduced Electron Transfer Reactions of High Molecular Weight Polysilanes to Electron Deficient Sensitizers in Solution

DOI PDF 参考文献10件

抄録

Fluorescence of 9-cyanoanthracene (CA), 9,10-dicyanoanthracene (DCA) and triphenylpyrylium tetrafluoroborate (TPP+BF4−) was quenched by high molecular weight polysilanes in dichloromethane (CH2Cl2). The quenching process of fluorescence of sensitizer by polysilanes polymer framework was investigated by measuring quenching rate constant. Small quenching rate constants in the order of 108–109 mol−1 dm3 s−1 were observed for high molecular weight polysilanes, however observation of transient absorption spectrum of pyryl radical (TPP·) was the direct evidence of electron transfer from polysilanes to TPP+.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 21 (11), 2131-2134, 1992

    公益社団法人 日本化学会

参考文献 (10)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ