Total Synthesis of (−)-Laurequinone

DOI DOI PDF 15 References
  • Takahashi Hironobu
    Institute of Pharmacognosy, Faculty of Pharmaceutical Sicences, Tokushima Bunri University
  • Tonoi Yasutoshi
    Institute of Pharmacognosy, Faculty of Pharmaceutical Sicences, Tokushima Bunri University
  • Matsumoto Keiji
    Institute of Pharmacognosy, Faculty of Pharmaceutical Sicences, Tokushima Bunri University
  • Minami Hiroyuki
    Institute of Pharmacognosy, Faculty of Pharmaceutical Sicences, Tokushima Bunri University
  • Fukuyama Yoshiyasu
    Institute of Pharmacognosy, Faculty of Pharmaceutical Sicences, Tokushima Bunri University

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Description

The first synthesis of (−)-laurequinone, cyclolaurane-type sesquiterpenoid isolated from the red alga Laurencia nidifica, has been achieved by using an intramolecular Heck reaction and an insertion of carbene as the key steps for the construction of quaternary carbon at the benzylic position and cyclopropane ring, respectively.

Journal

  • Chemistry Letters

    Chemistry Letters 27 (6), 485-486, 1998

    The Chemical Society of Japan

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