2-Vinylpyridine as Film-forming Additve to Suppress the Degradation of Carbon Anode by Dissolved Manganese for C/LiMn2O4 Rechargable Battery

DOI PDF 被引用文献5件 参考文献8件

書誌事項

タイトル別名
  • 2-Vinylpyridine as Film-forming Additve to Suppress the Degradation of Carbon Anode by Dissolved Manganese for C/LiMn<SUB>2</SUB>O<SUB>4</SUB> Rechargable Battery

この論文をさがす

説明

For lithium-ion batteries of C/(spinel Li–Mn–O), the sever capacity loss occurs after storage of the battery at >50 °C. This is mainly due to degradation of the carbon which was induced by electroreduction of Mn(II) dissolved from the spinel; this step is followed by the irreversible electrochemical reaction at the graphite/(Mn deposits)/electrolyte interface. However, 2-vinylpyridine as an additive into the electrolyte was capable of suppressing this degradation of graphite anode, therefore, improved the battery performances. During the first charge, electropolymerization of 2-vinylpyridine from about 0.9 V vs Li/Li+ resulted in film formation of poly(2-vinylpyridine) on the anode surface. The polymer protected the graphite from dissolved Mn(II).

収録刊行物

  • Chemistry Letters

    Chemistry Letters 31 (12), 1236-1237, 2002

    公益社団法人 日本化学会

被引用文献 (5)*注記

もっと見る

参考文献 (8)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ