PHOTOOXIDATION OF <i>p</i>-METHYLBENZYL ALCOHOL BY OXYGEN, CATALYZED BY FLAVIN ANALOGUES (3-METHYL-10-PHENYLISOALLOXAZINE AND 3-METHYL-10-PHENYL-5-DEAZAISOALLOXAZINE) IN THE PRESENCE OF Mg2+ ION

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  • Fukuzumi Shunichi
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Kuroda Sadaki
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Tanaka Toshio
    Department of Applied Chemistry, Faculty of Engineering, Osaka University

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  • PHOTOOXIDATION OF <I>p</I>-METHYLBENZYL ALCOHOL BY OXYGEN, CATALYZED BY FLAVIN ANALOGUES (3-METHYL-10-PHENYLISOALLOXAZINE AND 3-METHYL-10-PHENYL-5-DEAZAISOALLOXAZINE) IN THE PRESENCE OF Mg<SUP>2+</SUP> ION
  • ChemInform Abstract: PHOTOOXIDATION OF P‐METHYLBENZYL ALCOHOL BY OXYGEN, CATALYZED BY FLAVIN ANALOGS (3‐METHYL‐10‐PHENYLISOALLOXAZINE AND 3‐METHYL‐10‐PHENYL‐5‐DEAZAISOALLOXAZINE) IN THE PRESENCE OF MAGNESIUM(2+) ION

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説明

Flavin analogues (3-methyl-10-phenylisoalloxazine and 3-methyl-10-phenyl-5-deazaisoalloxazine) catalyze the photooxidation of p-methylbenzyl alcohol by oxygen in the presence of Mg2+ ion in acetonitrile to yield p-methylbenzaldehyde and hydrogen peroxide under irradiation of the visible light of λ>360 nm.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 13 (8), 1375-1378, 1984-08-05

    公益社団法人 日本化学会

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