Hg(OTf)2-catalyzed Cycloisomerization of Aryl- and Hetero-substituted 1,3-Dienes

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  • Yamamoto Hirofumi
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Shiomi Shinya
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Odate Daiki
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Sasaki Ikuo
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Namba Kosuke
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Imagawa Hiroshi
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Nishizawa Mugio
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University

Bibliographic Information

Other Title
  • ChemInform Abstract: Hg(OTf)<sub>2</sub>‐Catalyzed Cycloisomerization of Aryl‐ and Hetero‐Substituted 1,3‐Dienes.

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Description

We developed Hg(OTf)2-catalyzed Friedel–Crafts-like cycloisomerization of 7-arylhepta-1,3-dienes to give propenyl-substituted tetrahydronaphthalenes in excellent catalytic turnover under very mild conditions. 1,3-Dienyl sulfonamides and 1,3-dienyl alcohols were also efficiently cyclized to afford heterocyclic compounds.

Journal

  • Chemistry Letters

    Chemistry Letters 39 (8), 830-831, 2010

    The Chemical Society of Japan

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