溶融炭酸塩型燃料電池のガスリサイクル運転特性

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  • Molten Carbonate Fuel Cell Stack Performance with Gas Recycling
  • ヨウユウ タンサンエンガタ ネンリョウ デンチ ノ ガス リサイクル ウンテン

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Molten carbonate fuel cell (MCFC) power plant is expected to be one of the most promising future power generaton system for the electric utilities because of its high efficiency, environmental suitability and capability of using coal as fuel. To get such attractive performance, it is necessary for the plant to adopt the gas recycling operation system. The authors tested a 6 kW class MCFC stack with three types of gas recyclings such as cathode, anode and carbon dioxide ones, including pressurized conditions.<br>This paper describes the test results and the effects of the gas recycling operations. Cathode gas recycling is proved to be able to control the stack temperature and give the flexibility for setting oxygen utilization. Anode gas recycling is proved to be able to suppress the methane formation and decrease the deviation of the stacked cell voltages. Including the starting-up process, it is proved that the electricity can be generated from the stack without supplying carbon dioxide from outside the system by carbon dioxide gas recycling. In such a process using burner for carbon dioxide gas recycling, burner temperature must be controlled in the certain value. It is important to adjust the fuel supplying rate, load current and cathode gas recycling ratio each other. At load change process, constant gas utilization operation is effective not to change the burner temperature.

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