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- 臼井 博明
- 東京農工大学 大学院工学府
書誌事項
- タイトル別名
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- Interface Control of Organic Devices by using Self-Assembled Monolayers
- ジコ ソシキカマク オ モチイタ ユウキ デバイス カイメン セイギョ
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抄録
Interface between inorganic electrode and organic layer bears various problems, such as poor adhesion strength and charge injection barrier due to inconsistency in physicochemical properties of both materials. This paper reviews the experimental results of using self-assembled monolayers (SAMs) that have reactive terminal groups to resolve the problems of organic/inorganic interface. Polymer thin films that are covalently tethered to inorganic surfaces can be prepared by vapor-depositing monomer molecules on the substrates that were modified with SAMs having a function of polymerization initiator. The reactive units can be amino group for ring-opening polymerization, azo group for UV-assisted vinyl polymerization, and benzophenone unit for thermally-assisted vinyl polymerization. A polymer thin film prepared by spin-coating can also be tethered via a benzophenone-terminated SAM by photochemical reaction. The chemical tethering at the interface resulted in increase of adhesion strength, improvement of surface morphology, and increase of charge injection from the inorganic substrates.
収録刊行物
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- 電気学会論文誌C(電子・情報・システム部門誌)
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電気学会論文誌C(電子・情報・システム部門誌) 135 (2), 140-145, 2015
一般社団法人 電気学会
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詳細情報 詳細情報について
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- CRID
- 1390001204608393472
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- NII論文ID
- 130004870127
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- NII書誌ID
- AN10065950
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- ISSN
- 13488155
- 03854221
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- NDL書誌ID
- 026099477
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可