銅配向基板を用いたYBa2Cu3O7-δ超電導線材の微細構造観察

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タイトル別名
  • Microstructural Observation of YBCO Superconducting Tape with Textured Cu Substrate
  • ドウハイコウ キバン オ モチイタ YBa2Cu3O7 d チョウデンドウセンザイ ノ ビサイ コウゾウ カンサツ

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The microstructure of YBa2Cu3O7-δ (YBCO) superconducting wire with textured Cu substrate was investigated using an electron back scattering pattern (EBSP) and transmission electron microscopy (TEM). The structure of this wire is YBCO/CeO2/YSZ/CeO2/electro-plated Ni/textured Cu/SS. The YBCO film with Jc of 3.2 MA/cm2 was prepared for this observation. The crystallographic orientation relationship between the Ni layer and the Cu layer was investigated. The good cube-on-cube epitaxy including the position and the direction of the grain boundaries were confirmed. In addition, the clear layered structure and fact that there were no out-of-phase components were confirmed. From the electron beam diffraction, the crystallographic orientation relationship was confirmed as YBCO(006)//CeO2(002)//YSZ(002)//CeO2(002)//Ni(002) and YBCO(200)//CeO2(220)//YSZ(220)//CeO2(220)//Ni(200). From the results of energy dispersive X-ray spectrometry (EDS), the diffusion of Ni and Cu were confirmed. The need to optimize the Ni-layer thickness was suggested.

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  • 低温工学

    低温工学 45 (12), 514-519, 2010

    公益社団法人 低温工学・超電導学会 (旧 社団法人 低温工学協会)

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