The Molecular Solid from a Viewpoint of Photo-Induced Phase Transition and Related Phenomena

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  • NAKAMURA Toshikazu
    Division of Electronic Properties, Institute for Molecular Science School of Physical Sciences, The Graduate University of Advanced Studies
  • FURUKAWA Ko
    Division of Electronic Properties, Institute for Molecular Science School of Physical Sciences, The Graduate University of Advanced Studies

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  • 光誘起相転移・光誘起現象の観点から迫る分子性固体
  • ヒカリ ユウキ ソウテンイ ヒカリ ユウキ ゲンショウ ノ カンテン カラ セマル ブンシセイ コタイ

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Abstract

In this paper, we introduce the electronic states and electronic properties of molecular solid especially charge transfer salts and radical salts in the aspect of photo-induced phase transition and related phenomena. The characteristic features of molecular solid, which deeply related to photo-induced phase transition, are as following:(1) low-dimensional electronic states originated from anisotropic interaction,(2) strong electronic correlation induced by low carrier concentration,(3) lattice softness which causes competition of electronic phases with pressure and thermal contraction,(4) internal-freedom, namely, molecular motions. We propose strategies for exploring possible candidates for forthcoming materials with photo-induced phase transition.

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