Synthesis of New Di-Cation Type Stationary Phases for High Performance Anion-Exchange Chromatographic Separation of Carbohydrates
-
- Kadumi Kadumi
- Department of Human Environmental Science, Ochanomizu University
-
- YAMAZAKI Kaori
- Department of Chemistry, School of Science, Kitasato University
-
- KITAHARA Kei-Ichi
- Department of Chemistry, Tokyo Medical University
-
- AIKAWA Yoshihiro
- Department of Human Environmental Science, Ochanomizu University
-
- ARAI Sadao
- Department of Chemistry, Tokyo Medical University
-
- MASUDA–HANADA Takako
- Department of Chemistry, Tokyo Medical University
Bibliographic Information
- Other Title
-
- 新規なジカチオン型高速液体クロマトグラフィー用充填剤の合成とその糖分析への応用
- シンキ ナ ジカチオンガタ コウソク エキタイ クロマトグラフィーヨウ ジュウテンザイ ノ ゴウセイ ト ソノ トウ ブンセキ エ ノ オウヨウ
Search this article
Abstract
New anion-exchange di-cation type stationary phases D6Cm (m = 1, 6, 10, 14) having two quaternary nitrogen atoms were synthesized in two steps : first from the reaction of chloromethylated styrene-divinylbenzene copolymer and N,N,N',N'-tetramethyl-1,6-diaminohexane to give monocation-type stationary phase, D6, with a quaternary nitrogen atom ; then by the reaction of D6 with alkyl methanesulfonates having different alkyl chain lengths. The ion-exchange capacities of D6 and D6Cm were determined by Mohr method. The separation of all aldopentoses was successfully performed on the new stationary phases, D6Cm, using 0.1 M NaOH eluent.
Journal
-
- BUNSEKI KAGAKU
-
BUNSEKI KAGAKU 60 (12), 959-964, 2011
The Japan Society for Analytical Chemistry
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1390001204662421248
-
- NII Article ID
- 10030038609
-
- NII Book ID
- AN00222633
-
- NDL BIB ID
- 023372968
-
- ISSN
- 05251931
-
- Text Lang
- ja
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed
