Thermodynamics of Non-stoichiometric Compounds.

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  • Tsuji Toshihide
    Center for New Materials, Japan Advanced Institute of Science and Technology

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Other Title
  • 不定比化合物の熱力学
  • フテイヒ カゴウブツ ノ ネツリキガク

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Abstract

Themodynamics of non-stoichiometric compounds, mainly having a fluorite type crystal structure, is briefly reviewed in terms of phase diagram and defect structures at high temperature, standard formation enthalpy and heat capacity, effect of lattice constants on chemical composition of non-stoichiometric compounds doped with various cations, thermal expansion and mechanical properties such as Debye temperature, Grüneisen constant and adiabatic bulk modulus.

Journal

  • Netsu Sokutei

    Netsu Sokutei 27 (2), 88-99, 2000

    The Japan Society of Calorimetry and Thermal Analysis

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