起電力法によるZn‐Te合金の活量測定

書誌事項

タイトル別名
  • Activity measurements of Zn-Te alloys by EMF method.

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説明

The e. m. f. of galvanic cells with the solid electrolyte (ZrO2(+Y2O3)) was measured to determine the activity of zinc at the temperatures 839-988K in the two phase regions of zinc-tellurium alloys. The cells used were as follows:<br>Kanthal|Re|Zn, ZnO|ZrO2(+Y2O3)|ZnTe+Zn, ZnO|Re|Kanthal;<br>Kanthal|Re|ZnTe-Te, ZnO|ZrO2(+Y2O3)|air, Pt.<br>The e. m. f. method with fused salt electrolyte was also used for the alloy of ZnTe-Te.<br>The results were presented by the equations:<br>logaZn=2.365-7419.4/T/K for ZnTe-Te and<br>logaZn=-0.012+9.408/T/K for ZnTe-Zn alloy.<br>The solubility limit of Zn-Te system at 873K was determined, and the free energy of formation of ZnTe was derived from the data in this study. The result was compared with published ones.

収録刊行物

  • 熱測定

    熱測定 18 (2), 53-57, 1991

    日本熱測定学会

詳細情報 詳細情報について

  • CRID
    1390001205086697728
  • NII論文ID
    130003658470
  • DOI
    10.11311/jscta1974.18.53
  • COI
    1:CAS:528:DyaK3MXlt1Whu7Y%3D
  • ISSN
    18841899
    03862615
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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