Cationic Ring-opening Reaction of Polynorbornenes having Five-Membered Cyclic Carbonate Moiety

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  • 五員環環状カーボナート骨格を有するポリノルボルネン類のカチオン開環架橋反応挙動
  • 5インカン カンジョウ カーボナート コッカク オ ユウスル ポリノルボルネンルイ ノ カチオンカイカン カキョウ ハンノウ キョドウ

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The reaction behavior of polyalkenamers with 5-memberd cyclic carbonate 3 was examined. In the case of polymer 3 on cationic ring-opening with higher molecular weight (Mw) than ca. 5500, the cationic ring-opening reaction proceeded to give the corresponding DMSO-insoluble networked polymer. In addition, the degree of the volume change on the crosslinking was suggested to be controllable by the Mw and structure of polymer.

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