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- UYAMA Hiroshi
- Department of Materials Chemistry, Graduate School of Engineering, Kyoto University
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- KOBAYASHI Shiro
- Department of Materials Chemistry, Graduate School of Engineering, Kyoto University
Bibliographic Information
- Other Title
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- 架橋基を持つポリエステルの酵素合成
- カキョウキ オ モツ ポリエステル ノ コウソ ゴウセイ
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Abstract
Recent topics on in vitro synthesis of polyesters by lipase catalysis are reviewed. Lipase, an enzyme catalyzing an ester bond-cleavage reaction by water in living cells, induces the reverse reaction of hydrolysis, leading to polymer production by a bond-forming reaction. Polyester syntheses have been achieved from various monomer combinations, typically oxyacids or their esters, dicarboxylic acids or their derivatives/glycols, and lactones under mild reaction conditions. By utilizing characteristic catalytic function of lipases, enantio-, regio-, and chemoselective polymerizations proceed to give functional polymers, many of which are difficult to synthesize by conventional methods.
Journal
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- Journal of Network Polymer,Japan
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Journal of Network Polymer,Japan 23 (2), 113-122, 2002
Japan Thermosetting Plastics Industry Association
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Details 詳細情報について
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- CRID
- 1390001205088666496
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- NII Article ID
- 130003389543
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- NII Book ID
- AN10521608
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- ISSN
- 13420577
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- COI
- 1:CAS:528:DC%2BD38Xls1ylsLk%3D
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- NDL BIB ID
- 6193485
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- CiNii Articles
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- Abstract License Flag
- Disallowed