窒素侵入型化合物Nd<sub>2</sub>Fe<sub>17</sub>N<sub>3</sub>単結晶の磁気異方性

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タイトル別名
  • Magnetic Anisotropy in Single Crystals of an Interstitially Modified Nitrogen Compound, Nd<sub>2</sub>Fe<sub>17</sub>N<sub>3</sub>
  • 窒素侵入型化合物Nd2Fe17N3単結晶の磁気異方性
  • チッソ シンニュウガタ カゴウブツ Nd2Fe17N3 タンケッショウ ノ ジ

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抄録

Single crystals of an interstitially modified nitrogen compound, Nd2Fe17N3, were successfully synthesized for the first time by means of the high-pressure N2 gas nitrogenation technique. High-field magnetization curves along the rhombohedral principal axes for the Nd2Fe17 and Nd2Fe17N3 single crystals at 4.2 K indicated strong anisotropic behaviors, which were analyzed on the basis of a single-ion Hamiltonian including the Zeeman energy, exchange energy, and crystalline electric field (CEF) effect. The results indicate that the second-order CEF coefficient A20 reaches up to −1.5 × 103 K/a20 at 4.2K upon nitrogenation, which is about three times as large as that for Nd2Fe17.

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