書誌事項
- タイトル別名
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- Development of Analyzer for Photoluminescence Quenching in a Solid Matrix.
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An analyzer called "Q-chanG4" was developed with Visual Basic for photoluminescence quenching in a solid. This software can analyze the quenching mechanism in a solid matrix using emission decay curves and Stern-Volmer plots. Photoluminescence quenching of Tris(2, 2'-bipyridine)ruthenium(II) in a polyethylene glycol solid by methylviologen was analyzed with Q-chanG4. The quenching mechanism was determined as a combination of a dynamic quenching and a static quenching involving multi-step equilibria and dynamic quenching. The dynamic quenching rate constant in the polyethylene glycol was as large as that in an aqueous solution, suggesting that the diffusion coefficient of molecules in the polyethylene glycol is almost the same as that in an aqueous solution in spite of the solid state.
収録刊行物
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- Journal of Computer Chemistry, Japan
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Journal of Computer Chemistry, Japan 1 (1), 37-46, 2002
日本コンピュータ化学会
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詳細情報 詳細情報について
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- CRID
- 1390001205180008576
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- NII論文ID
- 10022553486
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- NII書誌ID
- AA11657986
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- COI
- 1:CAS:528:DC%2BD38XlvFSktr4%3D
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- ISSN
- 13473824
- 13471767
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可