Tunneling Effect of O<sub>2</sub> in Dissociative Adsorption on Pt(111) Surface
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- Shimizu Koji
- Department of Applied Physics, Osaka University, Japan
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- Diño Wilson Agerico
- Department of Applied Physics, Osaka University, Japan Center for Atomic and Molecular Technologies, Osaka University, Japan
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- Kasai Hideaki
- Department of Applied Physics, Osaka University, Japan Center for Atomic and Molecular Technologies, Osaka University, Japan
説明
Dissociative adsorption processes of O2 molecule on Pt(111) surface are explored using quantum dynamical calculations based on coupled-channel method. The explored adsorption sites are the direct dissociative adsorption channels, where the precursor state for O2 sticking are absent, with certain amount of activation barrier. We find that the dissociative sticking probability of O2 depicts the sigmoidal (S-shaped) curve in all cases which is a manifestation of the tunneling effect. Moreover, the sticking curve is sensitively dependent on the shape of the activation barrier which affects the width of the transition region. Molecular vibration facilitates sticking and affects the width of the barrier. [DOI: 10.1380/ejssnt.2013.72]
収録刊行物
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- e-Journal of Surface Science and Nanotechnology
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e-Journal of Surface Science and Nanotechnology 11 (0), 72-75, 2013
公益社団法人 日本表面真空学会
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詳細情報 詳細情報について
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- CRID
- 1390001205185840256
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- NII論文ID
- 130004933781
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- ISSN
- 13480391
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可