Formation of Molecular Chlorine by the Decomposition of 1, 2-Dichloroethane over Ru Supported on Titania-Silica

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  • チタニアシリカ担持ルテニウム触媒上での1,2-ジクロロエタン分解による分子状塩素の生成

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Abstract

Decomposition of 1, 2-dichloroethane was examined over Ru, Rh, Pd, Pt, Cu, and Cr catalysts supported on TiO2-SiO2 in air. A large amount of Cl2 was formed over Ru/TiO2-SiO2 catalyst at 400°C, whereas Rh, Pd, and Pt catalysts did not produce Cl2 even at 450°C. Although Cu and Cr catalysts also produced Cl2 effectively, the maximum activity observed at 650°C was still lower than that of Ru at 400°C.

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