Conversion of Ethanol into Propylene over TON Type Zeolite
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- Tsunoji Nao
- Dept. of Applied Chemistry, Graduate School of Engineering, Hiroshima University
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- Furumoto Yoshiyasu
- Dept. of Applied Chemistry, Graduate School of Engineering, Hiroshima University
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- Ide Yusuke
- Dept. of Applied Chemistry, Graduate School of Engineering, Hiroshima University
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- Sadakane Masahiro
- Dept. of Applied Chemistry, Graduate School of Engineering, Hiroshima University
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- Sano Tsuneji
- Dept. of Applied Chemistry, Graduate School of Engineering, Hiroshima University
Bibliographic Information
- Other Title
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- TON型ゼオライト上でのエタノール転化によるプロピレン合成
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Abstract
TON type zeolites with different SiO2/Al2O3 ratios (57, 81, 112, and 140) were synthesized using 1,6-diaminohexane, n-butyl alcohol, and 1-ethylpyridinium bromide as structure-directing agents, and the catalytic performance of protonated forms for conversion of ethanol into light olefins such as ethylene, propylene, and butenes was investigated. Although the yields of light olefins were dependent on the SiO2/Al2O3 ratios of the HTON type zeolites and the reaction conditions such as temperature and contact time, the relatively high propylene yield of ca. 25 C-% was obtained. HTONs with higher SiO2/Al2O3 ratios exhibited longer catalyst life. These results strongly indicate that TON type zeolite with 10-membered rings (0.46 nm × 0.57 nm) and only straight channels has high potential for the production of propylene from ethanol. The catalytic performance of HTON type zeolite was slightly improved by strontium modification.
Journal
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- Journal of the Japan Petroleum Institute
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Journal of the Japan Petroleum Institute 56 (1), 22-31, 2013
The Japan Petroleum Institute
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Details 詳細情報について
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- CRID
- 1390001205189267584
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- NII Article ID
- 10031166881
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- NII Book ID
- AA11590615
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- COI
- 1:CAS:528:DC%2BC3sXjslyiug%3D%3D
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- ISSN
- 1349273X
- 13468804
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- NDL BIB ID
- 024188320
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed