Crystal Structure of Monoaquobis (1,10-phenanthroline)nickel(II) Chloride

LIU He, LIU Li-Ping, ZHONG Bo-Hua

doi:10.2116/analscix.20.x63

Crystal Structure of Monoaquobis (1,10-phenanthroline)nickel(II) Chloride

DOI Web Site

LIU He

No.7 Department, Beijing Institute of Pharmacology and Toxicology
LIU Li-Ping

Department of Chemistry, Hebei Normal University
ZHONG Bo-Hua

No.7 Department, Beijing Institute of Pharmacology and Toxicology

書誌事項

公開日: 2004

DOI

10.2116/analscix.20.x63

公開者: 社団法人日本分析化学会

説明

The title complex [Ni(phen)₂(H₂O)Cl]Cl·H₂O·CH₃CN (phen = 1,10-phenanthroline) has been synthesized in solid phase reaction and characterized by X-ray diffraction analysis. The Ni(II) center is six-coordinated in a distorted octahedral geometry. The complexes form a dimeric structure through the two O-H…Cl hydrogen bonds, and neighboring π-π interactions link the dimer segments into a quasi-two-dimensional structure.