1, 3, 2-オキサアザホスホリジン2-スルフィド類および1, 3, 2-ベンゾジオキサホスホリン2-スルフィド類の光学異性体の殺虫活性

呉 少勇, 武谷 立子, 江藤 守総, 富澤 長次郎

doi:10.1584/jpestics.12.221

1, 3, 2-オキサアザホスホリジン2-スルフィド類および1, 3, 2-ベンゾジオキサホスホリン2-スルフィド類の光学異性体の殺虫活性

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呉少勇

Department of Agricultural Chemistry, Kyushu University
武谷立子

Department of Agricultural Chemistry, Kyushu University
江藤守総

Department of Agricultural Chemistry, Kyushu University
富澤長次郎

National Institute of Agro-Environmental Sciences

書誌事項

タイトル別名

Insecticidal Activity of Optically Active 1, 3, 2-Oxazaphospholidine 2-Sulfides and 1, 3, 2-Benzodioxaphosphorin 2-Sulfides
1,3,2オキサアザホスホリジン2-スルフィド類および1,3,2-ベンゾジオキサホスホリン2-スルフィド類の光学異性体の殺虫活性〔英文〕
1 3 2 オキサアザホスホリジン 2 スルフィドルイオヨビ 1 3 2 ベ

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説明

Optical isomers of ten 1, 3, 2-oxazaphospholidine 2-sulfides and two 1, 3, 2-benzodioxaphosphorin 2-sulfides, including a commercial insecticide, salithion, were topically applied to an organophosphate-susceptible strain of housefly. Of all the oxazaphospholidines, (S)_C(R)_P isomers showed the highest insecticidal activity, and the potency decreased with configuration in the order of (S)_C(R)_P>(S)_C(S)_P>(R)_C(R)_P>(R)_C(S)_P. In the benzodioxaphosphorins, the (S)_P configuration was favorable for high insecticidal activity. Some optical isomers were also tested against the onion maggot, two species of planthopper and an organophosphateresistant strain of housefly. The relationship between configuration and insecticidal activity was similar in the susceptible and resistant strains of housefly, but varied with species of insect.