1,4-ベンゾジオキサン環をもつ<i>N</i>-置換-2-ピペリドン類のヒエ種子発芽に対する阻害活性
-
- 塚田 英孝
- Laboratory of Pesticide Chemistry, Department of Applied Genetics and Pest Management, Faculty of Agriculture, Kyushu University
-
- 山田 直隆
- Laboratory of Pesticide Chemistry, Department of Applied Genetics and Pest Management, Faculty of Agriculture, Kyushu University
-
- 橋本 和樹
- Laboratory of Pesticide Chemistry, Department of Applied Genetics and Pest Management, Faculty of Agriculture, Kyushu University
-
- 谷口 栄二
- Laboratory of Pesticide Chemistry, Department of Applied Genetics and Pest Management, Faculty of Agriculture, Kyushu University
-
- 桑野 栄一
- Laboratory of Pesticide Chemistry, Department of Applied Genetics and Pest Management, Faculty of Agriculture, Kyushu University
書誌事項
- タイトル別名
-
- Inhibitory Activity of <i>N</i>-Substituted-2-piperidones with a 1, 4-Benzodioxan Ring on Germination of Barnyardgrass
- Inhibitory Activity of N-Substituted-2-piperidones with a 1,4-Benzodioxan Ring on Germination of Barnyardgrass
この論文をさがす
抄録
A variety of 3-substituted-2-piperidones and related compounds were evaluated for their activity to inhibit germination of barnyardgrass (Echinochloa utilis) seeds. 3-[1-(1, 4-Benzodioxan-6-yl)-1-hydroxymethyl]-N-benzyl-2-piperidone (22) showed extremely high inhibitory activity. Studies on the structure-activity relationship indicated that a 1, 4-benzodioxan ring, a hydroxy substituent at the α-position of the benzyl group and a 2-piperidone ring were significant for higher activity. Of the compounds tested, 3-[1-(1, 4-benzodioxan-6-yl)-1-hydroxymethyl]-N-cinnamyl-2-piperidone (55) was the most effective, showing more than 90% germination inhibition at 1 nM. In both compounds 22 and 55, only erythro isomers inhibited germination of barnyardgrass seeds, while threo isomers were inactive even at 1μM. This result indicated that the stereochemistry of 1, 4-benzodioxan moiety in the erythro isomer, which is fixed by an intramolecular hydrogen bond between the hydroxy group and the carbonyl group, was essential for activity. The erythro-22 and 55 were less active against rice seeds when compared to barnyardgrass.
収録刊行物
-
- 日本農薬学会誌(Journal of Pesticide Science)
-
日本農薬学会誌(Journal of Pesticide Science) 26 (2), 143-148, 2001
日本農薬学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390001205210698496
-
- NII論文ID
- 110001713238
-
- NII書誌ID
- AN00196227
-
- ISSN
- 03851559
- 13490923
- 1348589X
-
- NDL書誌ID
- 5777582
-
- データソース種別
-
- JaLC
- IRDB
- NDL
- Crossref
- NDL-Digital
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可