除草剤 bromobutide の水中における光分解

DOI NDLデジタルコレクション 日本農学文献記事索引 Web Site Web Site 被引用文献4件
  • 高橋 尚裕
    Laboratory of Biochemistry and Toxicology, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.
  • 三上 信可
    Laboratory of Biochemistry and Toxicology, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.
  • 山田 宏彦
    Laboratory of Biochemistry and Toxicology, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.
  • 宮本 純之
    Laboratory of Biochemistry and Toxicology, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.

書誌事項

タイトル別名
  • Photodegradation of the Herbicide Bromobutide in Water
  • 除草剤bromobutideの水中における光分解〔英文〕
  • ジョソウザイ bromobutide ノ スイチュウ ニ オケル ヒカリ ブン

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Photodegradation of bromobutide [N-(1-methyl-1-phenylethyl)-2-bromo-3, 3-dimethyl-butanamide], (P1), in water was studied using 14C preparations labeled separately at the phenyl ring or carbonyl group. Upon exposure to sunlight, P1 was photodecomposed with half-lives of ca. 13 weeks in distilled water, 12 weeks in sea water, 11 weeks in paddy field water and 1.3 weeks in 2% aqueous acetone. The photoreactions involved were oxidation at one of the gem-dimethyl or tert-butyl methyl group, hydroxylation at the phenyl ring, substitution of bromine by hydroxyl group, cleavage of the amide, carbon-bromine or benzylic carbon-nitrogen bond, and photomineralization of the phenyl and carbonyl carbon to 14CO2. Most of the photochemical reactions can be rationalized by a mechanism involving free radical intermediates. The carbon-bromine bond cleavage and photomineralization to 14CO2 were predominant in any water tested. The hydroxylation at the phenyl ring was much enhanced by UV irradiation of P1 in distilled water containing hydrogen peroxide or by treatment with Fenton's reagent, and consequently involvement of hydroxyl radical in the reaction was suggested. However, singlet molecular oxygen was unreactive to P1.

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