M<sub>0.5</sub>Bi<sub>2.5</sub>Ta<sub>2</sub>O<sub>9</sub> (M=Na, K) セラミックスの合成及び強誘電特性

  • 駒形 和也
    奈良先端科学技術大学院大学物質創成科学研究科
  • 武田 博明
    奈良先端科学技術大学院大学物質創成科学研究科
  • 塩嵜 忠
    奈良先端科学技術大学院大学物質創成科学研究科

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タイトル別名
  • Synthesis and Ferroelectric Properties of M0.5Bi2.5Ta2O9 (M=Na,K) Ceramics.

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Bismuth layer-structured ferroelectrics (BLSFs), M0.5Bi2.5Ta2O9 (M=Na, K) were synthesized using a solidstate reaction. Na0.5Bi2.5Ta2O9 (NBT) single phase polycrystals were obtained by heating raw material powders at 1100°C. On the other hand, K0.5Bi2.5Ta2O9 (KBT) powder contained KTaO3 as a main impurity phase. Dense ceramics of NBT were prepared by considering Bi2O3 vaporization and using a binder. Result of dielectric and ferroelectric characterizations of the NBT ceramic were as follows: Curie temperature, TC=780°C, dielectric constant, εs=158, dielectric loss factor, tan δ=0.011 as measured at room temperature and 1MHz and the remanent polarization, Pr=15-18μC·cm-2. The Pr value is the largest among reported BLSFs that are composed of two perovskite layers.

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