The Preparation of a Magadiite-Polyacrylonitrile Intercalation Compound and Its Conversion to Silicon Carbide
-
- SUGAHARA Yoshiyuki
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
-
- SUGIMOTO Ken-ichi
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
-
- YANAGISAWA Tsuneo
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
-
- NOMIZU Yasuyuki
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
-
- KURODA Kazuyuki
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
-
- KATO Chuzo
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
Bibliographic Information
- Other Title
-
- マガディアイト-ポリアクリロニトリル層間化合物の合成と炭化ケイ素への変換
- マガディアイト ポリアクリロニトリル ソウカン カゴウブツ ノ ゴウセイ ト
Search this article
Abstract
A magadiite (layered polysilicate)-polyacrylonitrile (PAN) intercalation compound was first prepared to investigate its potential as a precursor for the synthesis of non-oxide ceramics by carbothermal reduction. Acrylonitrile monomer was intercalated and polymerized in the interlayer space of a C12H25N(CH3)3-magadiite complex. After the cyclization of PAN by the heat treatment in air, the compound was heated in Ar flow for 2h. Above 1300°C, β-SiC was formed without the formation of any crystalline SiO2 phases. Since the reactions of a magadiite-carbon mixture involved the formation of cristobalite, it was shown that SiO2 from magadiite was reduced to form β-SiC without crystallization, which was caused by the presence of PAN in the interlayer space.
Journal
-
- Journal of the Ceramic Association, Japan
-
Journal of the Ceramic Association, Japan 95 (1097), 127-133, 1987
The Ceramic Society of Japan
- Tweet
Details 詳細情報について
-
- CRID
- 1390001205248566144
-
- NII Article ID
- 110002313562
-
- NII Book ID
- AN00245650
-
- ISSN
- 18842127
- 00090255
-
- NDL BIB ID
- 3119000
-
- Text Lang
- ja
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed